Magnesium ion mobility in post-spinels accessible at ambient pressure

D. C. Hannah, G. Sai Gautam, P. Canepa, Z. Rong, and G. Ceder; Chem. Commun. 53, 5171-5174 (2017)


We propose that Ti-containing post-spinels may offer a practically-accessible route to fast multivalent ion diffusion in close-packed oxide lattices, with the caveat that substantial thermodynamic driving forces for conversion reactions exist.

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